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The NaH must be kept away from water. This ensures that the polymers produced would give a high percentage of yields. This will complex the sodium cation, keeping it from associating with the anionic nitrogen. The experiment can be extended by having the same or different students use varying ratios of NaH to caprolactam. Figure 3 The new molecule formed also has a negatively-charged nitrogen, an amine anion.



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While this is a neat party trick, it isn't used commercially because, first, acid chlorides are a lot more expensive than acids, and second, acid chlorides stink horribly, and are much more toxic than acids. In addition, the condensation polymerization produced hydrochloric acid as by-product and it neutralized the acid present in the system.
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